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At 10 mg/mL : The top two rungs exceed a single 100-unit barrel, so at 12.5 and 15 mg the volume must be split across two injections or the vial reconstituted at a higher concentration with less water

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The m/z values are consistent with the expected isotopic mass distribution pattern

The result is free Cu(I), which is a potent pro-oxidant, and a copper-free GHK peptide with reduced activity