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Considering that the inhibition of TrxR by electrophiles usually occurs through Michael addition, the electrophilic centres in NPs likely support their anticancer activity and synergistic effects by targeting the Trx/TrxR system [167] (Fig

The ability to generate the strong non-radical oxidant HOCl from H 2 O 2 in the presence of chloride ions, however, has been thought to be unique to MPO among the mammalian heme peroxidases, serving as a biochemical fingerprint for the presence of enzymatically active MPO in tissue [157, 158]

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