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Adding Equation 16.63 and Equation 16.64 and canceling H 2 CO 3 from both sides give the following overall equation for the reaction of CO 2 with water to give a proton and the bicarbonate ion: Equation 16.65 The K value for the reaction in Equation 16.65 is the product of the true ionization constant for carbonic acid ( K a ) and the equilibrium constant ( K ) for the reaction of CO 2 (aq) with water to give carbonic acid